@Article{publ_mods_00000037, author = {Modrow, Antje and Zargarani, Dordaneh and Herges, Rainer and Stock, Norbert}, title = {The first porous MOF with photoswitchable linker molecules}, journal = {Dalton Transactions}, year = {2011}, publisher = {Royal Society of Chemistry}, address = {London / Cambridge}, volume = {40}, number = {16}, pages = {4217--4222}, keywords = {MOF; switching}, abstract = {We synthesized a porous twofold interpenetrated MOF [Zn 2 (NDC) 2 (1)] (coined CAU-5) using 3-azo-phenyl-4,4{\textcent}-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO 3 ) 2 {\textperiodcentered} 6H 2 O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally and with an irradiation wavelength of l max = 440 nm.}, note = {http://xlink.rsc.org/?DOI=c0dt01629b}, issn = {1477-9226}, doi = {10.1039/c0dt01629b}, url = {https://macau.uni-kiel.de/receive/publ_mods_00000037}, url = {https://doi.org/10.1039/c0dt01629b}, file = {:https://macau.uni-kiel.de/servlets/MCRFileNodeServlet/macau_derivate_00000013/c0dt01629b.pdf:PDF}, language = {en} }