000K utf8 1100 $c2011 1500 eng 2050 urn:nbn:de:gbv:8-publ-379 2051 10.1039/c0dt01629b 3000 Modrow, Antje 3010 Herges, Rainer 3010 Stock, Norbert 3010 Zargarani, Dordaneh 4000 The first porous MOF with photoswitchable linker molecules [Modrow, Antje] 4209 We synthesized a porous twofold interpenetrated MOF [Zn 2 (NDC) 2 (1)] (coined CAU-5) using 3-azo-phenyl-4,4¢-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO 3 ) 2 · 6H 2 O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally and with an irradiation wavelength of l max = 440 nm. 4950 https://doi.org/10.1039/c0dt01629b$xR$3Volltext$534 4950 https://nbn-resolving.org/urn:nbn:de:gbv:8-publ-379$xR$3Volltext$534 4961 https://macau.uni-kiel.de/receive/publ_mods_00000037 5051 540 5550 MOF 5550 switching