000K  utf8
1100  $c2011
1500  eng
2050  urn:nbn:de:gbv:8-publ-379
2051  10.1039/c0dt01629b
3000  Modrow, Antje
3010  Herges, Rainer
3010  Stock, Norbert
3010  Zargarani, Dordaneh
4000  The first porous MOF with photoswitchable linker molecules  [Modrow, Antje]
4209  We synthesized a porous twofold interpenetrated MOF [Zn 2 (NDC) 2 (1)] (coined CAU-5) using 3-azo-phenyl-4,4¢-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO 3 ) 2 · 6H 2 O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally and with an irradiation wavelength of l max = 440 nm.
4950  https://doi.org/10.1039/c0dt01629b$xR$3Volltext$534
4950  https://nbn-resolving.org/urn:nbn:de:gbv:8-publ-379$xR$3Volltext$534
4961  https://macau.uni-kiel.de/receive/publ_mods_00000037
5051  540
5550  MOF
5550  switching