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Dissertation

Chemoselective Cross-Coupling Reactions as Tools in Synthesis and Applications...

A nucleophile-selective cross-coupling reaction with vinyl and alkynyl bromides on a dinucleophilic thiophene bearing two metal groups, a boronic ester and a stannyl group, has been developed. The first nucleophilic site to react is the stannyl group, and subsequently, a Suzuki–Miyaura cross-coupling...