Molybdenum Tricarbonyl Complexes Supported by Linear PNP Ligands: Influence of P‐ and N‐Substituents on Relative Stability, Stereoisomerism and on the Activation of Small Molecules

Molybdenum tricarbonyl complexes supported by PNPhP ligands with terminal alkyl substituents were synthesized. Surprisingly, all of these complexes are found in the fac configuration, irrespective of the steric demand of the alkyl substituents. This is due to the fact that mer-fac isomerization is hindered.

Rights

Use and reproduction:


CC BY-NC-ND 4.0

Please note that individual components of the publication may be subject to other licensing or copyright conditions.

Cite

Citation style:
Could not load citation form.