Novel oxygen optode sensor with fast response time: an in-depth characterization and assessment of the HydroFlash O2, applicable for several ocean observing platforms

Optics-based sensors, called optodes, for oxygen are used for routine operations on autonomous instrumentation and profiling platforms with great success. Observations of oxygen gradients with high spatial and temporal resolution become increasingly important, while shortcomings still exist, namely, time constant problems, stability issues, or accuracy levels, that limit leveraging their full scientific and operational potential. Here, we demonstrate the utility of a novel, although currently not commercially available optode, the HydroFlash O2. It was manufactured by Kongsberg Maritime Contros GmbH between 2014 and 2019, and peer-reviewed studies illustrate its use until today. Our work comprises its first integrated characterization with data from 13 HydroFlash O2 optodes assessing oxygen, temperature, salinity and hydrostatic pressure dependence, long-term stability and drift, response time, and air-calibration compatibility. We multi-point calibrated this optode up to a root mean square error (RMSE) of <1 µmol L-1 (mean RMSE: 1.79 ± 0.50 µmol L-1), depending on the fit model type. Our laboratory setup yielded a temperature-dependent response time of τ63% = 3.31 ± 0.58 s, showing no significant difference between a weakly turbulent and turbulent flow, and was at least 50 % faster compared to the two most common optodes in oceanography, i.e., 4330 (Aanderaa) and SBE 63 (Sea-Bird Scientific). We assessed its pressure dependence between 0–5797 dbar, yielding an overall factor of 2.372 ± 0.409 % per 1,000 dbar based on three multi-point calibrated, drift-corrected optodes and five CTD (conductivity - temperature - depth) profiles. Ship-underway, mooring, and CTD-cast applications promise high-quality observations, including fast oxygen level changes.[...]

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