Tetrakis(diisopropyl amide) substituted norbornadiene and quadricyclane are highly barium selective ligands

Winkler, Torsten; Bayrhuber, Monika; Sahlmann, Benjamin; Herges, Rainer ORCID

Tetrakis(diisopropyl amide) substituted norbornadiene and quadricyclane derivatives were investigated for their extraction and transport capabilities with alkaline earth metal cations. Both amides exhibited a remarkably high preference of Ba2+ over any other alkali metal or alkaline earth cation. The binding geometries were determined by quantum chemical DFT calculations.

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Winkler, Torsten / Bayrhuber, Monika / Sahlmann, Benjamin / et al: Tetrakis(diisopropyl amide) substituted norbornadiene and quadricyclane are highly barium selective ligands. 2012.

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